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My solution
For me the problem was resolved by setting two services to run Manually, insted of Automatic (Delayed):
* Windows Mobile-based device connectivity
* Windows Mobile-2003-based device connectivity
In the first place, Sync Center started to appear at startup after I installed Windows Mobile Device Center and set it to syncronize with my Windows Mobile phone. I think, Sync Center can appear for different reasons. Mine had nothing to do with Offline files.